I think the top 2 are definitely 'Into the Renaissance' and 'Wonders of the Ancient World'
That said there really should be a proper 'Age of Empires' scenario that runs from 600BC - 0AD starting in the classical era that puts Rome, Carthage, Greece, Assyria, Babylon, Persia & Egypt on a map that spans the mediterranean through to the fertile crescent.
Assyria, Babylon & Persia would have established empires with head starts with immediate access to unique units but their UAs would be quite limited while Carthage, Greece and Rome start more isolated with only 1 city and take a bit longer but would have much more powerful unique attributes.