King is the standard AI difficulty (this is the AI difficulty for online play). And note I use the term "difficulty" very loosely.
Emperor is just like King except it gets a +20% production bonus.
Deity is just like King except it gets a +40% production bonus.
If you play GotW, the higher difficulty levels give the AI additional advantages, like starting with a Barracks, Bronze Working, Iron Working and a Great Leader.
The only adjustment you should make jumping from emperor to deity is to bear in mind the AI can produce even more. But its behavior is just the same. It will still attack with one legion army all the way into the modern era, settle its GA instead of flipping your city, settle cities in dumb places, expand only a little, etc.
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