First 100 Turns in Civilization V Gods & Kings?

He's probably building two scouts. That's what I do. If you're not on a map that supports this (IE Standard Pangaea) then pre-building the worker is viable.
 
How do you get pottery in time to build the granary after the scout? You should have 5 turns of production to burn, do you start the worker then switch to granary?

Yes (although it should just be 4 more turns, assuming you grow a pop point), or do double scout as noted above.
 
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