Thank you. It seems most others (merkin, uppi, souron) were missing Perf's point. It has nothing to do with experimental incertitude, Quantum Mechanics or this being a thought experiment.
Quantum mechanics is certainly involved here and needs to be considered: The forces between the atoms and molecules are quantum mechanical forces and have an uncertainity assiociated to it. Sum up the maximum of all these forces and you get the static friction coefficient, which should still have some uncertainity to it. Thus the "exact" coefficient of static friction is not defined, the only thing you can give are approximations.
If I say, let my "static coefficient of tallness" be my height, then this coefficient of tallness is exactly my height, BY DEFINITION. Sure I can't measure either it or my height exactly, yet they are still perfectly equal!
No, they're not: Your height changes over the day (I think it's around 0.5-2 cm). So a "coefficient of tallness" can not be defined more accurate than maybe 0.5 cm. It would be possible to measure the height accurate to 1 µm, but that would not make much sense, as that value would be wrong an hour later.