Nitrogen fluoride does not easily form on its own, though, so there would not be much of an effect.
The first thing that would happen is that the fluorine would react explosively with the water in the atmosphere, removing all the water (resulting in a much smaller greenhouse effect). Then almost everything else on the surface will start burning or corroding, depending on the material.
IIRC fluor is the most electronegative element.
Nitrogen is the most abundant gas in the atmosphere (and also very not-electronegative), so I guess a lot of covalent bonds between those two would be made
I don't know, but I have a feeling that everything dying is going to matter a lot more than whatever chemical processes the fluor can start
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