Did you tech BW yet? That's really what you should be teching now. fishing not doing much for you at present. Which Persian are you?
If you knew saw the fish before settling I might have settled 1E on the gold.
You have a few choices here. I like 3 spots just SE...all would work but I don't see all the map. Starting 1SE of the Gold tile (1NW of cows), you could settle that tile or each of the 2 tiles S of that tile. Each spot gets an instant trade route and the second border pop would give the city the fish too. The first two spots can use the cows, while the lowest spot can work corn immediately. Working corn immediately is probably the best, but that corn could be used for another city farther S, but I can't see what is down there. Regardless, either of those cities spots are immediately productive and connected.
Another interesting option is 2N of the gold N of cap. The idea here is that this city works the gold indefinitely until borders can be popped later for fish and corn. Less productive city early on but keeps a gold working early which is huge boost to commerce and tech. There are some forest next to the spot for chopping at least. (Nice spot to work gold early as cap won't be able to work all that gold while whipping stuff and running scientist later.)
Those are the first spots that come to mind for me. Something over to the E with corn and all those flood plains make for a great Bureau cap.
Probably 3 or 4 spots in that area to the SW/W/NW of Cap that can be settled at your leisure.
Oh..and knowing where copper is would really help...Not sure I see horses either.
Edit: On second thought for that N city you could ignore that fish and actually settle on the tile the bear is on. It's a Plains hill with immediate access to corn and then city can work a gold as well. Fish is in the ocean and can be accessed by a number of spots. You might get it later with a city to the E of it, or Joao settles over there first and you don't get it any way cause he beats you to border pop. 1E of corn is the better option really.
Might actually settle that first to get corn improved and work a gold faster, as the city will actually be pretty productive. Then another city to the SE)
why do you have two scouts and not one warrior?