My Documents > My Games > Sid Meier's Civilization 5 > Saves > Single
(if other than single player game it will be under one of the other options for last choice)
It took me a while to find it the first time so I created a shortcut on my desktop. That way whenever I download a start file I just open the shortcut and drag it right into the folder without having to find it each time.
If you're using mods, the save game will be in Documents/My Games/Sid Meier's Civilization 5/MODDEDSAVES/single (Modded saves won't be capitalized - just wanted to emphasize that slight difference).
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