I have exactly the same problem - and also on Win10 and Steam. according to another source, on steam the files are in a different location:
System
Location
Windows
%USERPROFILE%\Documents\My Games\Sid Meier's Civilization 5\Saves\
macOS (OS X)
~/Documents/Aspyr/Sid Meier's Civilization...
From another source: the save locations for different OSs (note it's different for Steam)
System
Location
Windows
%USERPROFILE%\Documents\My Games\Sid Meier's Civilization 5\Saves\
macOS (OS X)
~/Documents/Aspyr/Sid Meier's Civilization 5/Saves/
Linux
$XDG_DATA_HOME/Aspyr/Sid Meier's...
I am having exactly the same problem. also on Win10 and running a digital version off Steam. tried running as an admin using the line "runas.exe/user:administrator" as a launch option for the game in steam. but alas... still no saving.
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