Thermaltake Toughpower, I put this computer together myself.
Seems that it may have something to do with ATI drivers - as even the newest one has documented problems with Civ5.
I have almost same specs as you, and this happens to me with all leaders, though only one or two leaders per save. Completely dead computer for no reason. Shouldn't be possible for the game to crash everything!
Looking forward to see if someone can explain this behaviour.
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