There are a few possible explanations for this:
1. Mansa hates your team member (if you have one) or possibly your vassal (although that is unlikely)
2.You are close to victory and he does not want to help you win.
3.Aggressive AI is on (not sure about this one, dont normally use it)
I have seen this before (with Mansa coincidentally) when i was building my spaceship; He would not trade me plastics because i was his worst enemy, despite being pleased towards me.