There is a faction called the Peacekeepers. They don't keep the peace beyond opposing the repeal of the UN charter. It can be fun to play as them and role-play their peacekeeping role.
The Alpha Centauri equivalent of the United Nations is called the Planetary Council. You can use it to propose and vote on resolutions. The game also contains a faction called the Peacekeeping Forces, or the Peacekeepers, for short. Their ideology represents the humanitarian principles of the United Nations. As far as I know, the game doesn't contain anything called a "peacekeeping mission," however.
If you have any interest in playing the game, you can buy it for 6USD from Good Old Games. See post #4 in this thread for a link.
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