Steam still sells it for Windows only, but I don't think it's available as a legal download for the Mac.
The most likely place to find it would be at GameAgent, which is Aspyr's online store. However, I think the Civ3 Mac software depends on using the DVD for copy protection, so you can only buy the DVD there.
It seems to work fine with some minor cosmetic glitches (unit deaths not animated, wrong sound for some artillery pieces, lines appearing across menus etc.)
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