There are only 9 regular polyhedrons possible, and only 6 of these resemble a globe shape. (The others are "star shaped".) 4 of these 6 are made up of triangles (the other two, the cube and the dodecahedron, are made up of squares and pentagons, respectively. Long story short, making a solid figure out of congruent hexagons is
PHYSICALLY IMPOSSIBLE
I see...
One last vestige of hope for this idea, insipired by
this picture: notice how rare are pentagons on those geodesic grids, rare to the point i couldnt locate one. One possibility that crossed my mind is that these grids of the Earth haves only two pentagons, one at each pole.
This possibility makes a lot of sense. If im not mistaken, those grids were built to allow the use of finite differences to solve differential equations. AFAIK, finite differences cant handle irregular grids (that being the domain of finite elements), the grid must be regular and neatly arranged.
An interpretations of this is that there are pentagon-shaped "holes" in that globe. This means those "globes" are not closed surfaces, and therefore not restricted to the laws of regular polyhedrons. Those "holes" are of course singularities which are not considered in the calculations. However, as long as there are only two of them, one of each sitting at each pole, they are acceptable "aberrations", since most of the interesting results involve areas farther away from the poles.
The same thing can be said of civilization world maps: It would be undesirable to build cities EXACTLY at the poles, since they should be surrounded by ice glaciers which are normally associated with unproductive land. Of course it would suck to travel with planes and rockets through the poles and spot that pentagon-shaped "hole" in the world, but its more of an aesthetic issue.
Of course, it remains to be proven that 1000+ hexagons plus 2 pentagons can build a sphere-like closed surface.