More powerful engines. Sometimes the mainsail is not enough. You could install more mainsails but there are better alternatives: Dont know exactly which mod it is, since i dowloaded and installed many things simultaneously but it could be the "KW mod" or something. It comes with some nice stuff. For me it was also a hard task to build my main launcher. Finally the winner design is this:
It uses several short and powerfull stages with some large solid booster in the first one. Everything packed in six symetry around the payload, not under it. Max payload to LEO is around 150 tons. Very stable.
Ah, one thing more, to launch big wider rockets you need to get rid of the large red launch tower at the launching pad, of course there is a mod (i like mods) for it too, you can look for it some pages back in this very thread.
BTW here is a first attempt on my pure ion powered vessel: