I have never had an issue until today. I click on CIVV and I get preparing to launch but nothing happens. I can start CivIV and Company of Heroes with no problem.
Please try at first the steam file validation option: In Steam go library -> games -> civ5 -> rightclick -> properties -> check integrity of the game files.
Because it might be that some for the startup needed file got broken, and this will hopefully fix it.
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