If it's a definition and axioms I'd imagine it can't be proven. Axioms are the minimal set of things you need to assume to derive all the needed results.
I thought I'd wait until someone tried to demonstrate this before supplying what I've got, but since you said this, I may as well do this now. Sometimes, if not often, or even usually, in an axiomatic system it might come as possible to derive those axioms from another set of axioms with fewer axioms. For example, if we fit
the first definition by the Wolfram site used to define a Boolean Algebra to fit what we had above, we would have three more axioms
B5: a^(b^c)=(a^b)^c, a v (b v c)=(a v b) v c. (associativity)
B6: a^(a v b)=a, a v (a ^ b)=a. (absorption)
B7: a^a=a, a v a=a (idempotence).
These all come as derivable from B1-B4, as Whitesitt's book shows, a few Schaum's outlines show for a few of B5-B7 or all of them (Boolean Algebra, Abstract Algebra, Set Theory and Related Topics, Discrete Mathematics), and the Wolfram page cited above implies.
One could also state a^1=1^a in B2, but this comes as derivable given a^b=b^a. On to the demonstration.
If T(a, b)=T(b, a), and we replace T with ^, then a^b=b^a. If S(a, b)=S(b, a), and we replace S by v, then a v b=b v a. So, B1 holds for ({0, 1}, T, S) or ({0, 1}, ^, v).
0 and 1 are distinct in [0, 1], so they are distinct in {0, 1} also. If T(a, 1)=a, and we replace T with ^, we have a^1=a. If S(a, 0)=a, and we replace S with v, we have a v 0=a. So, B2 holds.
Since a, b, and c each represent any number in {0, 1}, and we have a^1=a, we then have 0^1=0. By B1, and the symmetric property of equality, we have 0=0^1=1^0. By the transitive property of equality, 0=1^0. Consequently, for 1 we have 0 as its a' element with respect to ^. We also for 0 we have 1 as its a' element with respect to ^. Or more compactly, 1'=0, since 1^0=0, 0'=1 since 0^1=0. Since we have a v 0=a, we have 1 v 0=1. This implies 1'=0 as we had above for ^. Since a v b=b v a, 1 v 0=0 v 1. By the symmetric and transitive properties of equality, we have 1=0 v 1, which implies 0'=1 as we had above for ^. So, the a' elements match, and B4 also holds.
I only know how to check B3 on a case-by-case basis.
In the above paragraph we derived that 0=0^1=1^0, and 1=1 v 0=0 v 1. Since a ^ 1=a, we also have 1^1=1. Since a v 0=a, we also have 0 v 0=0. {0, 1} has only two elements. So, for each operation ^ or v or T or S, we have four possible inputs (0, 0), (0, 1), (1, 0), (1, 1), and two possible outputs 0 and 1. We've already determined the output of three inputs for ^, 0^1=1^0=1^1=1, and the output of three inputs for v, 0 v 0=0 v 1=1 v 0=0. So, we only need to determine the output of
0^0, and the output 1 v 1.
0<=1. So, T(0, 0)<=T(1, 0) by T2. T(1, 0)=0, so T(0, 0)<=0. Since T only gives outputs in {0, 1}, we then have T(0, 0)=0. Thus replacing accordingly we have 0^0=0. Also since 0<=1, S(0, 1)<=S(1, 1). S(0, 1)=1, so 1<=S(1, 1). Consequently, S(1, 1)=1, and by replacement of operations we have 1 v 1=1.
Since we have two elements, and three variables in B3 in each equation, we can now check all 2^3 cases for each equation.
0^(0 v 0)=0^0=0. (0^0) v (0^0)=0 v 0=0.
0^(0 v 1)=0^1=0. (0^0) v (0^1)=0 v 0=0.
0^(1 v 0)=0^1=0. (0^1) v (0^0)=0 v 0=0.
0^(1 v 1)=0^1=0. (0^1) v (0^1)=0 v 0=0.
1^(0 v 0)=1^0=0. (1^0) v (1^0)=0 v 0=0.
1^(0 v 1)=1^1=1. (1^0) v (1^1)=0 v 1=1.
1^(1 v 0)=1^1=1. (1^1) v (1^0)=1 v 0=1.
1^(1 v 1)=1^1=1. (1^1) v (1^1)=1 v 1=1.
So, a^(b v c)=(a^b) v (a^c).
0 v (0^0)=0 v 0=0. (0 v 0) ^ (0 v 0)=0 v 0=0.
0 v (0^1)=0 v 1=0. (0 v 0) ^ (0 v 1)=0^1=0.
0 v (1^0)=0 v 0=0. (0 v 1) ^ (0 v 0)=1^0=0.
0 v (1^1)=0 v 1=1. (0 v 1) ^ (0 v 1)=1^1=1.
1 v (0^0)=1 v 0=1. (1 v 0) ^ (1 v 0)=1^1=1.
1 v (0^1)=1 v 0=1. (1 v 0) ^ (1 v 1)=1^1=1.
1 v (1^0)=1 v 0=1. (1 v 1) ^ (1 v 0)=1^1=1.
1 v (1^1)=1 v 1=1. (1 v 1) ^ (1 v 1)=1^1=1.
So, a v (b^c)=(a v b) ^ (a v c). Consequently, B3 holds.
Therefore, if we have {0, 1} as the set B, T as ^, and S as v, then ({0, 1}, T, S), or ({0, 1}, ^, v) satisfies B1-B4.