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Of all the fanfic couples to exist, that's... certainly one of them
Note to mods: I know this is an extensive explanation of a fanfic story, but I'm politely answering another person's comment and I do have a rant in here somewhere.
Now, about Arthur and Hermione:
There's a subgenre of Harry Potter fanfiction involving a Ministry-ordered Marriage Law. According to the summary at the beginning of the story:
Teao said:
Six years after the fall of Voldemort, the Ministry of Magic introduce a new statute in an attempt to counter the falling birthrate. Unmarried witches and wizards are given six months to find a spouse, or one will be chosen for them.
Hermione’s happily settled into her life as a single witch: her work and her friends keep her busy enough. Arthur’s had six years to get used to being on his own, but when they’re matched by the new law, they’re going to have to overcome their differences and their previous relationship and learn to live with (and maybe even love?) each other.
Teao is the author of this story. Her premise is that Fred and George are okay, but both Molly and Bill died. So when the story begins, Arthur Weasley has been a widower for 6 years and is just under the 55-year age limit to marry. He could ask for an exemption, considering the number of children he's already fathered, but as he tells Hermione, he's found life without Molly rather lonely, particularly as all his children are now adults out on their own and it's just him living alone in the Burrow. He says he wants to marry again, so he's not opposed to the match, but would understand completely if Hermione doesn't want to marry someone old enough to be her father (Hermione was never able to undo the memory-loss spell she cast on her parents, so they're still living in Australia and unaware that they ever had a daughter).
Ron and Hermione were never a serious couple in this story. Hermione preferred to remain single and Ron marries Astoria Greengrass.
Hermione's first match was Draco Malfoy. This is not one of the stories where they get along, so they both reject the match. Her second match is Malfoy's friend Goyle. They hate each other as well. Hermione has to either take the third match or risk having to marry whoever the Ministry comes up with for the 4th one. And since Lucius Malfoy is due to be paroled from Azkaban soon, Hermione realizes that when Arthur Weasley's name comes up for the third match, she'd better accept, so she doesn't risk being matched with Lucius.
What Hermione expected from this marriage isn't how it's turning out. She didn't love Arthur at first and he's okay with that - all he wants from her is what she's willing to give (and they do have to have at least two children within 10 years to meet the requirements the Ministry has set down), and that she be faithful to him. But eventually she does come to love Arthur, and it's an interesting situation given the dynamics of not only her marriage, but the marriages of Arthur's children.
The marriage law doesn't care if a witch or wizard is LGBT. They expect people to marry and produce children.
It's a realistic (for HP) take on people who survived a horrific war, losing family and friends, dealing with PTSD, and trying to fix the broken parts of their society.
The story is currently 71 chapters, and Arthur and Hermione are visiting Arthur's brother Charlemagne, who lives in Saskatchewan with his extended family of children and grandchildren and
their families.
So as 'ships go, this is unusual. As a story, it's well-written and has a good balance of plot, character, good times and not-so-good times. Yes, it's a bit smutty in some chapters, but if that's not your (general 'your') thing, nothing plotwise will be lost by skipping over those parts (I usually do; I don't need a play-by-play of bedroom activities to enjoy a story, but this isn't something I've told the author in the conversations we've had in the comments section).
There are a lot of people who follow this story, and I look forward to the weekly updates - so it was upsetting to think we might not get this week's chapter. But the author was able to update, so now she's set me a puzzle... we got talking about naming characters and she's challenged us to figure out the themes she used for naming the characters in Charlemagne's extended family. It's fun; the author is Canadian, so this part of the story that's set in Canada is a treat. She asked for suggestions of Canadian musicians who were popular in the year 2005 or earlier, and of course I suggested the Irish Rovers. She incorporated one of their songs into the latest chapter, so that's a Rave-worthy thing - first time any fanfic author has incorporated one of my suggestions into a future chapter.
I have a "fanfiction recommendations" thread planned for A&E, and am working on the OP for that. This story will be among them, as it's quickly become one of my favorites.
But since this is the Rants thread, here's a minor rant: I told her about my King's Heir project and my problems with coming up with names for my own characters. She thinks I should keep the placeholder name of "Count Chocula" as his actual name. Thank you, no. I'm not naming someone living in an AU Britain in the year 1039 "Chocula." Nor will I name him Dracula or Vladimir. After nearly 5 years it's really frustrating not to have a name for this character.